Spectrophotometric determination of copper by TTA extraction

Spectrophotometric Determination of Copper

The utility of Patton and Reeder’s indicator, HHSNNA, for the trace spectrophotometric and visual colorimetric determination of Cu 2+ is explored. A wine red complex of composition 1:1 is found to be formed between Cu 2+ and HHSNNA. The complex has λmax at 530 nm with ε = 25,558 L mole -1 cm -1 and is stable for more than 2 hrs. Beer’s law is obeyed between 0 to 1.5 ppm. The developed procedure...

Selective extraction spectrophotometric determination

Extraction of Traces of Copper as Tetra-Butylammonium Tetrathiocyanato Copper (II) and Its Spectrophotometric Determination Using Eriochrome Black T

An extraction-spectrophotometric method for the determination of traces of copper (II) is described. The method is based on the quantitative extraction of copper as tetrabutylammonium tetrathiocyanato copper (II) into methyl isobutyl ketone, followed by spectrophotometric determination, using eriochrome black T as a metallochromic indicator. The red-violet mixed complex of copper absorbs at...

Spectrophotometric Determination of Copper Piperazine Dithiocarbamate

Spectrophotometric method for determination of cu(II) in the trace quantities was developed by using piperazine dithiocarbamate as ligand in ammonium chloride-ammonium hydroxide medium at pH -9.5. The procedure developed was applied for the estimation of cu(II) in microgram quantities in the water samples and the method developed was found to be simple and sensitive. Spectrophotometry is one of...

Spectrophotometric determination of palladium by extraction of its

A new method is proposed for naphthalene extraction and spectrophotometric determination of palladium at the ppm level with chinoform. The method is based on the formation of a yellow complex which is extractable by molten naphthalene and on the dissolution of the extract in dioxane. The yellow solution follows Beer's law at 462 nm over ~he range of 7 to 140 ~g of palladium per 10 ml of dioxane...